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Chemical Thermodynamics I: Thermodynamics and Statistical Mechanics

Develop an understanding of fundamental thermodynamic principles and how they arise from molecular scale system properties.

Chemical Thermodynamics I: Thermodynamics and Statistical Mechanics

Develop an understanding of fundamental thermodynamic principles and how they arise from molecular scale system properties.

This online course is the first in a series of two thermodynamics courses from the MIT Department of Chemistry. Together, they cover chemical thermodynamics, statistical mechanics, phase equilibria, and kinetics.

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In this course, you will explore the foundational principles of thermodynamics for chemical systems and how these principles connect to the properties of the molecules that comprise them. You will explore the laws of thermodynamics and how they combine to establish the relationships between entropy, energy, work, and heat flow. You will then leverage these relationships to understand the nature of equilibrium and the forces that drive spontaneous transformations. You will then be introduced to the field of statistical mechanics, which formalizes the molecular scale origins of thermodynamic principles. Finally, you will leverage your understanding of thermodynamics and statistical mechanics to explore fundamental applications, including heat engines, calorimetry, and equilibrium in multi-component systems.

What you'll learn

  • Energy and the First Law of Thermodynamics
  • Spontaneity and the Second and Third Laws of Thermodynamics
  • Statistical Mechanics
  • Chemical Potential and Applications of Thermodynamics

Prerequisites

Undergraduate General Chemistry recommended; Multivariable Calculus such as 18.02.1x

Meet your instructors

  • Featured image for Henrik Heelweg
    Graduate Student
  • Featured image for Adam P. Willard
    Francis Wright Davis Professor of Chemistry
  • Featured image for David Grimes
    Instructor and Digital Learning Scientist

Who can take this course?

Because of U.S. Office of Foreign Assets Control (OFAC) restrictions and other U.S. federal regulations, learners residing in one or more of the following countries or regions will not be able to register for this course: Iran, Cuba, Syria, North Korea and the Crimea, Donetsk People's Republic and Luhansk People's Republic regions of Ukraine.